Lecture 36: Review

author: Catherine L. Drennan, Department of Chemistry, Center for Future Civic Media, Massachusetts Institute of Technology, MIT
recorded by: Massachusetts Institute of Technology, MIT
published: Feb. 10, 2009,   recorded: December 2005,   views: 220
released under terms of: Creative Commons Attribution Non-Commercial Share Alike (CC-BY-NC-SA)

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I. Case Study: Methionine Synthase

A. Kinetics

1. Enzyme

2. Inhibition

B. Transition metals

1. Tetradentate ligand

2. d-electron count

3. Chelate effect


1. Steric number

2. Geometry

3. Angles

D. Oxidation / Reduction

II. Review

A. Reducing agent

B. Spontaneous reaction

C. ΔG°

III. Acid-Base Equilibrium

A. Deprotonation

B. pKa

C. Lewis acid

IV. Chemical Equilibrium

A. Conformational changes

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