Lecture 34: Kinetics (cont.)

author: Catherine L. Drennan, Department of Chemistry, Center for Future Civic Media, Massachusetts Institute of Technology, MIT
recorded by: Massachusetts Institute of Technology, MIT
published: Feb. 11, 2009,   recorded: December 2005,   views: 435
released under terms of: Creative Commons Attribution Non-Commercial Share Alike (CC-BY-NC-SA)

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I. Effect of Temperature on Reaction Rates

A. Gas-phase

1. Arrhenius equation

B. Activation energy, Ea

1. Using activation energy to predict a rate constant

C. Reaction Coordinate and the Activation Complex

1. Activated complex / transition state

2. Relationship between Ea and k

3. Relationship between ΔH and K

4. Rate constants and temperature

5. Equilibrium constants and temperature

6. Le Châtelier’s Principle

7. Large Ea vs. small Ea

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