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Designing of metal-organic frameworks towards water-resistant structures

Published on Feb 06, 2017457 Views

Matjaž Mazaj

Metal-organic frameworks (MOFs) are a fast developing class of nanoporous materials constructed from nodes of metal ions and multidentate organic ligands forming the crystalline hybrid nets. Their uni

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Chemistry

Chapter list

Designig of metal-organic frameworks towards water-resistant structures00:00
Metal-organic frameworks? - 100:19
Metal-organic frameworks? - 201:20
Control over03:39
Control over the functionalities - 103:59
Generation of free metal sites04:02
Control over the functionalities - 205:01
Incorporation of active species05:12
Control over the functionalities - 305:36
Ligand modification05:42
Structural diversity and ‘rational design’ opens almost unlimited application opportunities06:03
Field of research on MOFs06:36
MOF‘s applicability can be limited by their sensitivity to moisture07:54
Factors governing hydrostability - 109:33
Factors governing hydrostability - 209:49
Factors governing hydrostability - 310:18
Factors governing hydrostability - 410:51
Factors governing hydrostability - 511:10
Can we synthesize hydrostable MOF via ‘rational design‘?11:46
Zn-benzene-1,3,5-tricarboxylate - 113:32
Zn-benzene-1,3,5-tricarboxylate - 214:07
Zn-benzene-1,3,5-tricarboxylate - 314:53
Zn-benzene-1,3,5-tricarboxylate - 415:29
Zn-benzene-1,3,5-tricarboxylate - 516:25
Zn-benzene-1,3,5-tricarboxylate - 617:11
Cu3(BTC)2- HKUST-118:07
Approaches to increase stability of MOFs under humid conditions20:12
Enhanced hydrostability of MOFs21:17
Incorporation of MOF within silica matrix21:44
HKUST-1/FDU-12 - 123:36
HKUST-1/FDU-12 - 224:15
HKUST-1/FDU-12 - 324:50
HKUST-1/FDU-12 - 425:17
HKUST-1/FDU-12 - 526:44
HKUST-1/FDU-12 - 627:47
MOF/polyHIPE composite membrane28:36
MIL-100/polyHIPE - 230:25
MIL-100/polyHIPE - 430:54
MIL-100/polyHIPE - 131:34
MIL-100/polyHIPE - 331:42
MOF was used to stabilize polyHIPE32:01
Recrystallization of CuO@polyHIPE into HKUST1@polyHIPE - 132:30
Recrystallization of CuO@polyHIPE into HKUST1@polyHIPE - 232:51
Recrystallization of CuO@polyHIPE into HKUST1@polyHIPE - 233:07
Embedded MOFs are highly accessible33:36
What about hydrostability?34:23
Conclusions36:03
Acknowledgements36:56