MIT 5.60 Thermodynamics & Kinetics - Spring 2008

MIT 5.60 Thermodynamics & Kinetics - Spring 2008

36 Lectures · Feb 2, 2008

About

This subject deals primarily with equilibrium properties of macroscopic systems, basic thermodynamics, chemical equilibrium of reactions in gas and solution phase, and rates of chemical reactions.

Acknowledgements

The material for 5.60 has evolved over a period of many years, and therefore several faculty members have contributed to the development of the course contents. The following are known to have assisted in preparing the lecture notes available on OpenCourseWare:

Emeritus Professors of Chemistry: Robert A. Alberty, Carl W. Garland, Irwin Oppenheim, John S. Waugh.

Professors of Chemistry: Moungi Bawendi, John M. Deutch, Robert W. Field, Robert G. Griffin, Keith A. Nelson, Robert J. Silbey, Jeffrey I. Steinfeld. Professor of Bioengineering and Computer Science: Bruce Tidor. Professor of Chemistry, Rice University: James L. Kinsey. Professor of Physics, University of Illinois: Philip W. Phillips.

Course Homepage: 5.60 Thermodynamics & Kinetics Spring 2008

Course features at MIT OpenCourseWare page: *Syllabus *Lecture Notes *Readings *Exams *Download Course Materials

Complete MIT OCW video collection at MIT OpenCourseWare - VideoLectures.NET

Uploaded videos:

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46:46

Lecture 1: State of a system, 0th law, equation of state

Moungi G. Bawendi

Jun 15, 2009

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22662 Views

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50:42

Lecture 2: Work, heat, first law

Moungi G. Bawendi

Jun 15, 2009

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52:07

Lecture 3: Internal energy, expansion work

Robert W. Field

Jun 15, 2009

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54:36

Lecture 4: Enthalpy

Moungi G. Bawendi

Jun 15, 2009

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49:21

Lecture 5: Adiabatic changes

Moungi G. Bawendi

Jun 15, 2009

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52:21

Lecture 6: Thermochemistry

Keith A. Nelson

Jun 15, 2009

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Lecture 7: Calorimetry

Keith A. Nelson

Jun 15, 2009

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49:43

Lecture 8: Second law

Keith A. Nelson

Jun 15, 2009

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50:06

Lecture 9: Entropy and the Clausius inequality

Keith A. Nelson

Jun 15, 2009

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Lecture 10: Entropy and irreversibility

Keith A. Nelson

Jun 15, 2009

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Lecture 11: Fundamental equation, absolute S, third law

Keith A. Nelson

Jun 15, 2009

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Lecture 12: Criteria for spontaneous change

Keith A. Nelson

Jun 15, 2009

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Lecture 13: Gibbs free energy

Keith A. Nelson

Jun 15, 2009

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Lecture 14: Multicomponent systems, chemical potential

Moungi G. Bawendi

Jun 15, 2009

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51:20

Lecture 15: Chemical equilibrium

Moungi G. Bawendi

Jun 15, 2009

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51:54

Lecture 16: Temperature, pressure and Kp

Moungi G. Bawendi

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Lecture 17: Equilibrium: application to drug design

Moungi G. Bawendi

Jun 15, 2009

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Lecture 18: Phase equilibria — one component

Keith A. Nelson

Jun 15, 2009

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Lecture 19: Clausius-Clapeyron equation

Moungi G. Bawendi

Jun 15, 2009

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Lecture 20: Phase equilibria — two components

Moungi G. Bawendi

Jun 15, 2009

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Lecture 21: Ideal solutions

Keith A. Nelson

Jun 15, 2009

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Lecture 22: Non-ideal solutions

Keith A. Nelson

Jun 15, 2009

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Lecture 23: Colligative properties

Moungi G. Bawendi

Jun 15, 2009

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Lecture 24: Introduction to statistical mechanics

Keith A. Nelson

Jun 15, 2009

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51:28

Lecture 25: Partition function (q) — large N limit

Keith A. Nelson

Jun 15, 2009

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51:26

Lecture 26: Partition function (Q) — many particles

Moungi G. Bawendi

Jun 15, 2009

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Lecture 27: Statistical mechanics and discrete energy levels

Keith A. Nelson

Jun 15, 2009

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Lecture 28: Model systems

Keith A. Nelson

Jun 15, 2009

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51:30

Lecture 29: Applications: chemical and phase equilibria

Keith A. Nelson

Jun 15, 2009

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50:38

Lecture 30: Introduction to reaction kinetics

Keith A. Nelson

Jun 15, 2009

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45:18

Lecture 31: Complex reactions and mechanisms

Moungi G. Bawendi

Jun 15, 2009

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50:47

Lecture 32: Steady-state and equilibrium approximations

Moungi G. Bawendi

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Lecture 33: Chain reactions

Moungi G. Bawendi

Jun 15, 2009

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Lecture 34: Temperature dependence, Ea, catalysis

Moungi G. Bawendi

Jun 15, 2009

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50:37

Lecture 35: Enzyme catalysis

Moungi G. Bawendi

Jun 15, 2009

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40:09

Lecture 36: Autocatalysis and oscillators

Moungi G. Bawendi

Jun 15, 2009

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8473 Views

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